2,5-Dibenzoyl­benzene-1,4-diaminium dichloride

نویسندگان

  • Shui-Ping Deng
  • Shan Liu
  • Fei Yang
  • Ji-Ling Xu
  • Hong-Jun Zhu
چکیده

The asymmetric unit of the title compound, C(20)H(18)N(2)O(2) (2+)·2Cl(-), is composed of one-half of the 2,5-dibenzoyl-benzene-1,4-diaminium dication, located on a centre of inversion, and one Cl(-) ion. The dihedral angle between the central benzene ring and the benzoyl phenyl ring is 53.3 (2)°. In the crystal structure, ions are linked to form a two-dimensional network parallel to the (10) plane by N-H⋯Cl hydrogen bonds.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Butane-1,4-diaminium 2-(meth­oxy­carbon­yl)benzoate dihydrate

In the title compound, C(4)H(14)N(2) (+)·2C(9)H(7)O(4) (-)·2H(2)O, the butane-1,4-diaminium cation lies on an inversion center. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the components into layers parallel to (100). Addtional stabilization within these layers is provided by weak inter-molecular C-H⋯O hydrogen bonds.

متن کامل

1-[4-(3-{[5-(4-Chloro­phen­yl)furan-2-yl]methyl­idene­amino}-2,5-dioxoimidazol­idin-1-yl)but­yl]-4-methyl­piperazine-1,4-diium dichloride hemihydrate

The title compound, C(23)H(30)ClN(5)O(3) (2+)·2Cl(-)·0.5H(2)O, was synthesized by N-alkyl-ation of 1-({[5-(4-chloro-phen-yl)-2-furan-yl]methyl-ene}amino)-2,4-imidazolidinedione with 1-bromo-4-chloro-butane, and N-methyl-piperazine. In the crystal, the cations, anions and water mol-ecules are linked by O-H⋯Cl and N-H⋯Cl hydrogen bonds.

متن کامل

Efficient synthesis of β-hydroxy thiocyanates from epoxides and ammonium thiocyanate using 1,4-bis(triphenylphosphonium)-2-butene dichloride as a new catalyst

1,4-bis(triphenylphosphonium)-2-butene dichloride was developed as a new phase transfer catalyst. This quaternized phosphonium salt catalyzed the regioselective ring opening of epoxides by thiocyanate ion to give β-hydroxy thiocyanates in high yields under mild conditions.

متن کامل

2-Hydroxy-N,N′-diisopropylpropane-1,3-diaminium dichloride

In the crystal structure of the title amino alcohol derivative, C(9)H(24)N(2)O(2+)·2Cl(-), the cations and anions are linked by inter-molecular O-H⋯Cl and N-H⋯Cl hydrogen bonds into a three-dimensional network.

متن کامل

N 1,N 2-Di­methyl­ethane-1,2-diaminium dichloride

The cation of the title salt, C4H14N2 (2+)·2Cl(-), is located on a crystallographic inversion center and is bis-ected by a mirror plane, with one quarter of the C4H14N2 (2+)·2Cl(-) formula unit being crystallographically unique. he chloride ions also sit on a mirror plane. The conformation of the cation is a regular straight-chain conformation with all non-H atoms in anti positions. In the crys...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008